"why" can be compared to an old Latin form qui, an ablative form, meaning how. Today "why" is used as a question word to ask the reason or purpose of something. This use might be explained from a formula such as "How does it come that ...". If you meet an old friend of yours, whom you never expected to meet in town, you can express your surprise by saying: Why, it's Jim! This why in the ...
The usual order is "Why is this not [ready yet]?" Inverting it to "Why is not this [rose in bloom]?" might be possible in poetry, but it sounds awkward at best in everyday usage. Note: awkward at best is a euphemism for incorrect. Edit: you didn't ask about it, but for completeness I thought I'd mention that "Why isn't this [all over the internet]?" is perfectly fine; indeed, it's probably the ...
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